That looks like Jelena Karleusa on a very bad day
Anyway, the singer is called Anna Florinioti (Αννα Φλωρινιωτη) as for the title of the song my best bet is that it's called "papse pia na me koitas (πάψε πια να με κοιτάς)". She is a second class singer who has attempted to be the greek answer to America's Christina Aguilera, or (it seems) Serbia's Jelena Karleusa, but with very little success.